If the screen continues to mist up after cleaning then you may have a faulty sensor in the aircon. Could be worth having a diagnostic scan to check.
Cheers Spike
Thanks Spike. What is the sensor measuring and what action is being taken?
Note, there is another problem with the A2 which people sometimes get when driving. If the outside temp drops to +5 degrees then the inside of the windscreen can suddenly mist up with huge amounts of condensation. Quite sudden and scary. Dealer suggested the automatically controlled vents may be stuck open. A diagnostic scan apparently will show this. Maybe this could be the problem with condensation whilst parked.
I think I know what causes this to happen, specifically relating to 5 deg C. Most VAG auto climate systems turn the air con off below 5 deg C (I've had a Passat and Golf, currently have A2 + A6 all with essentially the same system). The dealers and handbooks say that this is to avoid "icing" in cold weather.
There is no way to force the compressor on and even when in Auto, at low temps the air con is off. You can tell it happens because you have to manually adjust the fan to keep the windows clear.
Not a useful feature IMO, you really need the air con on a cold wet day.